منابع مشابه
Dielectric Relaxation of Diethylsulfoxide
The dielectric loss spectrum of the title substance has been measured in its pure liquid state between 10 MHz and 72 GHz at 20°C. In comparison to the Debye function, it is slightly broadened towards the high frequency side. The maximum corresponds to a relaxation time of 51 ps. In view of the molecular size and viscosity, this is relatively long and thus indicative of associative intermolecula...
متن کاملDielectric Relaxation of Three
Relaxation spectra have been measured at 20°C for mono-, diand triethanolamine in the pure liquid state and in a 0.6 mole fraction mixture with 1,4-dioxane. The general resemblance to the dielectric behaviour of alcohols and aminoalcohols shows that relaxation is governed by association effects. In this regard, several features point to significantly differing behaviour of the mono compound in ...
متن کاملDielectric Relaxation Spectroscopy
C.M. Roland (December 17, 2014) Introduction Impedance spectroscopy and dielectric relaxation measurements yield the same information; however, their purpose and analysis methods differ. Impedance spectroscopy is typically used to probe electrochemical processes, while dielectric relaxation data, almost invariably expressed in the complex permittivity representation, provide information on dyna...
متن کاملDielectric Relaxation of Biological Water†
Dielectric relaxation and NMR spectrum of water in biological systems such as proteins, DNA, and reverse micelles can often be described by two widely different time constants, one of which is in the picosecond while the other is in the nanosecond regime. Although it is widely believed that the bimodal relaxation arises from water at the hydration shell, a quantitative understanding of this imp...
متن کاملDielectric relaxation in dimethyl sulfoxide/water mixtures studied by microwave dielectric relaxation spectroscopy.
Dielectric spectra of dimethyl sulfoxide (DMSO)/water mixtures, over the entire concentration range, have been measured using the transmission line method at frequencies from 45 MHz to 26 GHz and at temperatures of 298-318 K. The relaxation times of the mixtures show a maximum at an intermediate molar fraction of DMSO. The specific structure of mixtures in different concentration regions was de...
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ژورنال
عنوان ژورنال: Nature
سال: 1977
ISSN: 0028-0836,1476-4687
DOI: 10.1038/269631b0